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Combine sugar and lemon zest.
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Run a lemon wedge around glass, and dip rim into sugar, lemon mixture.
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To a cocktail shaker filled with ice add tequila, lemon juice, Cointreau and simple syrup.
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Shake until well chilled.
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Strain the mixture into your prepared cocktail glass.
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Garnish with lemon slice, sprinkled with sugar, lemon mixture.